Product ID:BLACO-TRON TMS PLUS
MSDS Date:09/01/1987
FSC:6850
NIIN:00D002048
MSDS Number: BBFPQ

BARON BLAKESLEE

2001 N-JANICE AVE
MELROSE PARK, IL 60160
US

Emergency Phone: 201-455-2000

Info Phone: 312-450-3900

Cage: 0FDJ7

BARON BLAKESLEE

MELROSE PARK, IL 60160 US

Telephone: 201-455-2000

Cage: 0FDJ7

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 91-92%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 4%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

NITROMETHANE

CAS: 75-52-5

RTECS: PA9800000

Fraction By Weight: 0.5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 9192

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 4%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 ABOUT 43 G/KG (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:LOW TOXICITY,MILD IRRITANT. IT IS AN
ANESTHETIC & INHALATION OF HIGH CONCENTRATIONS CAN PRODUCE
ASPHYXIATION. AT LEVELS OF ABOUT 2500 PPM IN AIR THERE BEGINS TO BE
INTERFERENCE WITH PSYCHOLOGICAL & PS YCHOMOTOR FUNCTIONS,EXPRESSED
AS EXCITEMENT & INCOORDINATION.
Effects of Overexposure:LOW CONCENTRATION:HEADACHE,DIZZINESS,NAUSEA;
HIGH CONC(>2500 PPM):INTOXICATION.CARDIAC EFFECTS,CENTRAL NERVOUS
SYSTEM DEPRESSION; EYE/SKIN:IRRITATION; ING:SIMILAR SYMPTOMS AS FOR
INHALATION.
Medical Cond Aggravated by Exposure:NONE STATED.

First Aid:INH:REMOVE TO FRESH AIR,GIVE MOUTH-TO-MOUTH RESUSCITATION IF
BREATHING HAS STOPPED,GIVE OXYGEN AS NECESSARY.DO NOT GIVE
ADRENALIN(EPINEPHRINE); ING:IF CONSCIOUS,INDUCE VOMITING BY GIVING
2-4 GLASSES O F WATER & TOUCH FINGER TO BACK OF THROAT,TAKE TO A
HOSPITAL; EYE:FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MIN,LIFTING
EYELIDS; SKIN:WASH WITH SOAP & WATER,REMOVE CONTAMINATED CLOTHING &
SHOES.

Extinguishing Media:USE PROPER EXTINGUISHING MEDIA FOR SURROUNDING
FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:WILL DECOMPOSE AT TEMPERATURE ABOVE 250F.

Spill Release Procedures:EVACUATE AREA.PROVIDE MAX
VENTILATION.UNPROTECTED PERSONNEL SHOULD STAY UPWIND OF SPILL.WEAR
PROPER PROTECTIVE CLOTHING.DIKE AREA & CONTAIN SPILL.PREVENT
CONTAMINATION OF GROUND & SURFACE WATER.USE SA WDUST OR
VERMICULATE,SWEEP INTO CONTAINER & CLOSE.

Handling and Storage Precautions:DO NOT USE IN POORLY VENTILATED
AREAS.KEEP CONTAINERS CLOSED WHEN NOT IN USE.AVOID CONTAMINATION OF
WATER SUPPLIES.
Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS.AVOID
CONTACT WITH EYES & SKIN.DO NOT TAKE INTERNALLY.DO NOT EAT,DRINK OR
SMOKE IN WORK AREAS.

Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
SITUATIONS. USE NIOSH-APPROVED PRESSURE-DEMAND SELF-CONTAINED OR
SUPPLIED-AIR RESPIRATOR WHERE THE PLACE IS CONFINED,OR ENCLOSED.
Ventilation:LOCAL EXHAUST FOR FILLING ZONES & MECHANICAL FOR STORAGE
AREAS.
Protective Gloves:RECOMMENDED
Eye Protection:SPLASH PROOF GOGGLES
Other Protective Equipment:EYE BATH & SAFETY SHOWER.
Work Hygienic Practices:USE NORMAL HYGIENIC PRACTICES.
Supplemental Safety and Health

HCC:N1
Boiling Pt:B.P. Text:103F/39.4C
Melt/Freeze Pt:M.P/F.P Text:<-31F/-35C
Vapor Pres:370
Vapor Density:5
Spec Gravity:1.46
pH:7
Evaporation Rate & Reference:10 (ETHER=1)
Solubility in Water:MODERATE (8.0%)
Appearance and Odor:COLORLESS LIQUID WITH ETHEREAL & FAINT SWEETISH
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & STRONG ALKALIS REACTIVE METAL:POWDERED
ALUMINUM,MAGNESIUM,ZINC,MOLTEN BARIUM,LITHIUM SHAVINGS,ETC.
Stability Condition to Avoid:AVOID TEMPERATURE ABOVE 250F.AVOID
SPARKS,HOT SPOTS,WELDING,FLAMES & CIGARETTES.
Hazardous Decomposition Products:HYDROCHLORIC ACID,HYDROFLUORIC
ACID,PHOSGENE

Waste Disposal Methods:CONTAMINATED ABSORBENT MAY BE DISPOSED OF IN A
PERMITTED HAZARDOUS WASTE FACILITY. RECOVERED LIQUID MAY BE
REPROCESSED OR INCINERATED OR TREATED IN A WASTE MANAGEMENT
FACILITY. FOLLOW FEDERAL,STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.